Subnet Mask:
- When applying an IP to an interface
- Routing protocol summary addresses
- BGP
- PIX security appliance ACL's
- ASA security appliance ACL's
- When creating DHCP pools on a Switch or Router
Wildcard Mask:
- EIGRP network statements
- OSPF network statements
- VPN concentrator network lists (when setting the local and remote allowed networks)
- Router ACL's
This list is not exhaustive and I will add to it as I come across new instances where you use either a Subnet mask or Wildcard mask.